Stainless steels come in various microstructures, from austenitic to ferritic or martensitic. Their corrosion-resistance makes them suitable for industries like oil and gas.
PWHT can be beneficial to lean grade SMSS services when it comes to sour service conditions; however, data regarding long term exposure are limited. PWHT requirements depend on grade and service conditions.
Weldability
Welding stainless steels requires different techniques than welding other metals. The type of welding process you select can impact both its corrosion resistance and porosity; using low energy processes may reduce deposition rates, leading to narrow weld bead that’s susceptible to rusting. When welding stainless steels it is essential to use a shield gas such as argon for protection against environmental influences that might otherwise impact on its welds.
There is an array of stainless steel alloys designed for specific uses, and each grade possesses unique microstructure and properties. As a result, fabrication rules vary for each grade: austenitic grades can be welded using any filler metal you prefer while ferritic and martensitic alloys require specific welding procedures with higher heat input to achieve satisfactory results. In order to produce acceptable duplex alloy results they require specific wire for welding in order to achieve acceptable outcomes.
Postweld heat treatment of stainless steel thickness sections must include postweld heat treatment to avoid sensitization. This is necessary because chromium reacting with carbon can form chromium carbides which result in intergranular corrosion, leading to intergranular corrosion of weld areas. Sensitization sensitivity can be reduced through preheating and controlled cooling prior to welding, according to welding procedure specifications (WPSs) and standards.
Carbon Content
Most stainless steel alloys contain very low levels of carbon. However, this can have an adverse effect on certain grades; carbon can make austenitic stainless steels vulnerable to inter-granular corrosion (IGSC), or IGSCC; furthermore a high carbon content can decrease corrosion resistance for some grades.
Stainless steel’s durability can be seen in some of the world’s most iconic buildings – from St Paul’s Cathedral in London, Paris Savoy Hotel canopy and New York Chrysler Building are among them – where its structural components require longevity.
Reaching optimal performance from stainless steel products often requires combining various alloying elements, such as chromium, molybdenum and nickel. While these alloys increase strength while improving corrosion resistance and mechanical properties, their main goal should be increasing strength without negatively affecting corrosion resistance or mechanical properties.
Alloying elements can assist with meeting the requirements for specific applications by altering the microstructure and contributing to fatigue resistance and corrosion resistance. To achieve strength and durability that meets those required of its intended use, alloying elements must be balanced carefully in their ratios.
Résistance à la corrosion
Corrosion resistance of stainless steel depends on its chemical composition, particularly its chromium content. Chromium reacts with oxygen to form an outer protective layer that limits air and water exposure while also helping prevent electrochemical reactions between the metal surface and corrosive chemicals that attack it from within. But this doesn’t make stainless steel immune from corrosion – depending on factors like chemical concentration, pH of solution pH levels and temperature which all affect its resistance ability.
All grades of stainless steel resist corrosion from phosphoric and nitric acids at normal temperatures, but higher-alloyed grades must be resistant to concentrated sulfuric and hydrochloric acids for effective protection. Localized corrosion such as pitting and crevice corrosion is possible, though less frequently seen than general oxidation.
Additives such as molybdenum can improve a stainless steel alloy’s resistance to certain corrosive chemicals and its surface can even be passivated for increased corrosion protection.
PWHT may be required for all stainless steels in certain applications to avoid sensitization and intergranular corrosion (IGC), particularly when exposed to high temperatures. PWHT’s role varies based on carbon content, chemical makeup of steel material and section thickness – with more stringent treatments required depending on carbon content or sensitization factors that could reduce strength or corrosion resistance in service.
Service Conditions
Stainless steels are extremely tough, boasting impressive strength-to-weight ratios and offering numerous properties that make them suitable for various applications and environments. Their lifespan depends on factors like their environment of placement, corrosion resistance level and alloy composition – typically, stainless steel lasts longer in dry inland locations with little exposure to pollutants or marine environments that cause corrosion; regular cleaning can extend its life as well.
Some grades of stainless steel can be difficult to work with, requiring special tools and skills for shaping or machining purposes. Furthermore, these materials can be susceptible to brittle failure if overstressed – something which should be kept in mind when using pressurized devices involving these materials as it could result in stress corrosion cracking.
Due to these considerations, it’s crucial that when working with this material it adheres to all specifications and guidelines relating to it. This means selecting an appropriate grade, reducing exposure time to hot temperatures, and only welding with professionals trained in its use. Post weld heat treatment typically isn’t needed on austenitic grades due to their resistance to brittle fracture; however, martensitic grades may require further heat treatments; adding nickel and molybdenum can reduce stress corrosion cracking risk in this regard.